Actually I have used both. Both have their good points and bad. Poker Office is laid out a little better and I find it easier to understand my stats. That said, it is limited in the number of room it accepts info from. Poker Tracker is a bit more complex and you really need to "teach" yourself how to fully utilize it. It has been around for quite a while and suggestions for improvement have been taken and implemented.
If I had to pick one I would have to say PokerTracker.
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