I'm not entirely sure what you are looking to do, but if you are looking to add sections to your website and add pages, you will need to use frontpage or dreamweaver. But to learn how to do that is beyond the scope of a thread on a forum, so you will need to play around and practice with the programs, possibly look up tutorials too.
If you just want them to be downloadable, you can just upload them to your public_html file and link to them. Therefore people can just right click > save file as, and download the files.
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